Vedatom Physics
Thermo / Expansion
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Heat & work — sign convention
First law: ΔQ = ΔU + ΔW — heat supplied = rise in internal energy + work done by the gas.
Heat Q: + when supplied TO the system, − when released.
Work W: + when done BY the gas, − on compression.
ΔU is a state function; Q and W depend on the path. Over a full cycle ΔU = 0.
Full walkthrough →
Thermo Lab · all topics
01 Module 01 · Thermodynamics

Thermometry & Thermal Expansion

Two ideas run through this whole chapter. First, temperature — a number that tells you how hot something is, which you can read off on any scale you invent. Second, thermal expansion — the fact that almost everything grows a little when heated and shrinks when cooled. Start at the top and work down: read a temperature on your own scale, see why solids stretch, then watch a rod, a sheet and a block grow.

§01

Temperature & how we measure it

A thermometer works by picking some property that changes steadily with heat — the length of a mercury column, the pressure of a trapped gas, the resistance of a wire — and reading it against a marked scale. To build any scale you only need two fixed points you can reproduce anywhere: usually melting ice and boiling water. Everything in between is just even spacing.

{{ tC }}
°C celsius
{{ tF }}
°F fahrenheit
{{ tK }}
K kelvin
drag temperature{{ tC }} °C
one point, three scales: C5 = F−329 = K−273.155
Kelvin is the absolute (thermodynamic) scale — it starts at −273.15 °C, where an ideal gas would exert zero pressure. A change of 1 °C = 1 K, so temperature differences are equal in both.
Relating any two scales — X and Y

Celsius, Fahrenheit and Kelvin are not special — you could invent your own scale °X or °Y and give the ice and steam points any numbers you like. The trick that ties them together is simple: the same physical temperature sits at the same fraction of the way up every scale. Ice is the bottom of all of them; steam is the top of all of them. So the fraction climbed must match.

In each scale, write L for its lower (ice) mark and U for its upper (steam) mark. Drag the temperature and watch the reading rise by the same fraction on all three bars.

{{ b.name }}
{{ b.reading }}
U {{ b.ufp }}
L {{ b.lfp }}
drag: fraction from ice → steam{{ celsiusReading }} °C
general rule — equal fractions θ − LU − L for X = θ − LU − L for Y
right now, live {{ celsiusReading }}100 = {{ xReadRaw }} − 10130 − 10 = {{ yReadRaw }} + 2080 + 20
All three equal {{ fracPct }} — the fraction of the climb. That single idea converts between every linear temperature scale, including the C–F–K formula above.
§02

Thermal expansion — why matter grows

Zoom into any solid and you find atoms held to their neighbours by bonds that behave like tiny springs. At absolute zero they sit still at a spacing r₀. Give them heat and they vibrate about that spot — the hotter it is, the wider they swing.

Here is the key: the bond is not symmetric. It is much harder to push two atoms together than to pull them apart — the energy well on the right is shallower than on the left. So as the swing gets wider, the atom spends more time far out than close in, and its average position drifts outward. Multiply that tiny outward drift over billions of atoms and the whole object gets measurably bigger. Cool it back down and the reverse happens — it contracts.

This is why the effect is small (bonds are stiff) but universal (every solid, liquid and gas has it) — and why a perfectly symmetric spring would not expand at all.

Bond energy vs spacing
U spacing r → cold hot avg → grows
Linear · α

A long, thin thing (rod, rail, wire) grows in length.

α = ΔLL₀ ΔT
ΔL = L₀ α ΔT
Areal · β

A flat sheet or plate grows in area — both sides at once.

β = ΔAA₀ ΔT = 2α
ΔA = A₀ (2α) ΔT
Volumetric · γ

A solid block or a liquid grows in volume — all three sides.

γ = ΔVV₀ ΔT = 3α
ΔV = V₀ (3α) ΔT

Why the neat ratio α : β : γ = 1 : 2 : 3? A cube of side L becomes L(1+αΔT) on each edge. Its volume scales as (1+αΔT)³ ≈ 1 + 3αΔT — the tiny α² and α³ terms are negligible — so volume grows three times as fast as length, and area (two edges) twice as fast.

⤡ fixed end (reference)
ΔL = {{ dLmm }} mm
L₀ = 1.000 m · dashed = original (drawn ×250 exaggerated)
plate A₀ = 1 m² · the hole grows with the metal (drawn exaggerated)
block V₀ = 1 m³ · dashed = original face (drawn exaggerated)
temperature change ΔT{{ expDTsigned }} °C
Hit {{ playLabel }} to heat and cool automatically. A positive ΔT expands; a negative ΔT (cooling) contracts by exactly the same rule.
{{ modeSymbol }} grows by {{ growthPct }} %
Material {{ matName }} · α = {{ alpha }} ×10⁻⁶ /°C. In this mode the coefficient is {{ modeCoeff }} = {{ modeCoeffVal }} ×10⁻⁶/°C.
β = {{ beta }} γ = {{ gamma }} ×10⁻⁶/°C
key: L₀ original length ΔL increase in length ΔT temperature change α linear coeff. (per °C) dashed outline = original size · left end is clamped
The ring & ball experiment

A classic classroom demo. A metal ball is machined to just barely pass through a metal ring. Now change the temperature and the fit changes — because both the ball and the ring's hole expand. This is the surprise most students miss: a hole expands exactly like the metal around it, as if it were filled in. Heat the ball or the ring, then drop it and watch smoothly.

cross-section of the ring · opening widens when heated
heat the ball · ΔT+{{ ballDTv }} °C
heat the ring · ΔT+{{ ringDTv }} °C
{{ rbHead }}

{{ rbBody }}

Shrink-fit trick: engineers heat the ring so its hole widens, slip it over a shaft, then let it cool to grip tight.
§03

Thermal stress

Clamp the same rod between two rigid walls so it cannot expand. The prevented expansion strain αΔT now shows up as a huge compressive stress — this is why rails and bridges need expansion gaps.

compressed
temperature rise ΔT{{ strDT }} °C
Rod cross-section A = 1 cm². Material: {{ matName }} (Y = {{ youngG }} GPa).
stress = Y α ΔT = {{ stressMPa }} MPa
force = stress × A = {{ forceKN }} kN
Independent of length! A 1 cm² steel rod heated {{ strDT }}°C pushes with {{ forceKN }} kN — enough to buckle a rail.
⚠ exceeds {{ matName }} yield (~{{ yld }} MPa) — the rod would deform or buckle.
§04

Anomalous expansion of water

Graph — density ρ of water vs temperature
Density ρ (kg/m³) → Temperature (°C) → 1000.0 997.8 0 10 20 max ρ @ 4°C
temperature{{ waterT }} °C · ρ ≈ {{ waterRho }} kg/m³
Why lakes freeze top-down

Water is densest at 4 °C, not 0 °C. As a pond cools, water at 4 °C sinks to the bottom; colder, lighter water stays on top and freezes first.

The ice layer then insulates the water below — so fish survive the winter. Between 0–4 °C water contracts on heating (negative γ); above 4 °C it expands normally.

Note the axis: the curve above plots density ρ (mass per unit volume), not pressure. It peaks — a maximum — at 4 °C.
Watch a lake freeze — top-down

Drag the surface temperature down from a mild day toward deep winter. Because water is densest at 4 °C, the coldest water can’t sink once it drops below 4 °C — so ice forms on top and grows downward, while a 4 °C layer stays safely at the bottom.

ICE · {{ iceLabel }}
{{ surfLabel }}
4 °C · densest, sinks
fish survive here ↓
surface / air temperature{{ lakeTv }} °C
−12 °C · deep winter+10 °C · mild
{{ lakeStageHead }}

{{ lakeStageBody }}

Going deeper

Bimetallic strip

Two metals with different α bonded together. Heat it — the higher-α metal (brass) grows more, so the strip curls toward the lower-α side (invar). Thermostats use this.

heatΔT = {{ biDT }} °C
■ brass (high α)■ invar (low α)
Pendulum-clock error

A pendulum rod expands in summer → longer L → larger period → the clock runs slow. Fractional time lost per day:

ΔT_periodT = ½ α ΔT

Lost time per day = ½ α ΔT × 86400 s. Invar (tiny α) is used for accurate pendulums.

Liquids: apparent vs real

A liquid sits in a container that also expands, so the observed (apparent) rise is less than the real one:

γreal = γapp + γvessel

The vessel's cubical expansion γvessel = 3αvessel must be added back to get the liquid's true expansion.

Warm-up

quick checks · tap a card to reveal · {{ warmChev }} to fold

Test your Understanding

10 single-correct · {{ examScore }}/10 correct · {{ examChev }} to fold
Q{{ e.n }}
{{ e.q }}
{{ e.verdict }}
{{ e.a }}
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